{Bis[2-(diphenyl­phosphino)eth­yl]phenyl­phosphine-κ3 P,P′,P′′}chloridopalladium(II) hexa­fluoridophosphate

نویسندگان

  • Paul R. Vorce
  • Susie M. Miller
  • Monte L. Helm
چکیده

In the title compound, [PdCl(C(34)H(33)P(3))]PF(6), the Pd(II) atom adopts a distorted PdP(3)Cl square-planar geometry arising from the P,P',P''-tridentate triphos ligand and a chloride ion.

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In the structure of the title compound, [Pd(C(19)H(21)N(2)P)(2)](PF(6))(2)·2.85CH(3)CN, the two six-membered NHC-phosphane chelate rings form a distorted square-planar coordination geometry around the Pd(II) atom, which lies 0.212 (1) Å above the coordination plane. The sum of the bond angles at Pd(II) is 358.3°, with C-Pd-P bite angles of 84.03 (10) and 83.54 (9)°. The structure includes three...

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عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009